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EDX (Energy-Dispersive X-ray Spectroscopy)

Definition: EDX is an analytical method for determining the elemental composition of materials by means of characteristic X-ray radiation. It is mostly used in combination with a scanning electron microscope (SEM). The method enables a spatially resolved qualitative and semi-quantitative elemental analysis.

Practical relevance: EDX serves to identify alloying elements, foreign particles, corrosion products or coating compositions. The detection limit is typically around 0.1-1 wt.-%, depending on the element and the detector system. Results are presented as a spectrum or element mapping. Limitations exist for light elements (e.g. H, He) and for very thin layers.

Decision-making perspectives:

  • Technical decision-makers: Verification of material compositions and root cause analysis in cases of failure.
  • Purchasing/project management: Verification of alloys or coatings conforming to specification.
  • Science: Combination with EBSD or WDX for in-depth microstructure and phase analysis.
  • Insurance/law: Documented elemental analysis to preserve evidence in the event of material deviations.

Typical testing or verification methods: SEM-EDX analysis, point analysis, line scan, element distribution mapping.

FAQ:

  • Can EDX determine the exact chemical composition?
  • EDX generally provides a semi-quantitative analysis; for high-precision determinations, supplementary methods are required.
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